Understanding the Equivalence Point in Titrations

Titrations are a fundamental technique in analytical chemistry that involves the determination of the concentration of an unknown substance by reacting it with a known quantity of a reagent. The purpose of titration is to find the equivalence point, where the moles of the unknown substance are equal to the moles of the reagent added. Understanding the equivalence point in titrations is crucial for accurate results and proper analysis. In this article, we will look at what the equivalence point is, how it is determined, and its significance in analytical chemistry.

What is the Equivalence Point?

The equivalence point in a titration is the point at which the stoichiometric amount of the titrant has reacted completely with the analyte. It is the point where the moles of the titrant added equals the moles of the analyte present in the sample. At this point, all the reactants in the mixture have been consumed, and only the products remain. This point is characterized by a sudden change in the properties of the solution, such as pH, conductivity, or color.

How is the Equivalence Point Determined?

There are different methods for determining the equivalence point, depending on the type of titration. The most common methods used include:

1. Colorimetric Indicators

Colorimetric indicators are substances that change color upon reaching a specific pH or when a particular chemical reaction occurs. They are added to the titration solution and change color when the equivalence point is reached. The color change is due to the difference in the chemical properties of the reactants and the products. Examples of colorimetric indicators include phenolphthalein, bromothymol blue, and methyl orange.

2. Potentiometry

Potentiometry involves measuring the potential difference between two electrodes in a solution to determine the concentration of the analyte. A pH meter or a potentiometer is used to measure the potential difference. At the equivalence point, the potential difference is zero since all the reactants have been consumed. Potentiometry is commonly used in acid-base and redox titrations.

3. Conductometry

Conductometry involves measuring the conductivity of a solution as the titrant is added to it. The conductivity of the solution increases as the concentration of ions in the solution increases. At the equivalence point, the conductivity of the solution stops increasing as all the ions in the solution have been consumed. Conductometry is commonly used to determine the endpoint in acid-base and precipitation titrations.

Why is the Equivalence Point Important?

The equivalence point is crucial in analytical chemistry as it helps to accurately determine the concentration of unknown substances. A slight deviation from the equivalence point can lead to significant errors in the results. For example, if excess titrant is added beyond the equivalence point, the excess reagent will react with other compounds in the analyte solution, leading to errors in the results.

Another reason why the equivalence point is important is that it helps to identify the endpoint, which is the point where the colorimetric indicator changes its color, or the potential difference measured by a potentiometer reaches its minimum value. The endpoint is not necessarily the same as the equivalence point, but it indicates the proximity of the endpoint to the true equivalence point.

Additionally, the equivalence point provides information about the stoichiometry of the reaction. The balanced chemical equation of the reaction can be determined from the volume of the reagent added to reach the equivalence point. This information is useful in determining the composition of the unknown substance.


Determining the equivalence point in titrations is essential in obtaining accurate and reliable results in analytical chemistry. The use of appropriate methods such as colorimetry, potentiometry, and conductometry aid in identifying the equivalence point and the endpoint. The equivalence point helps in determining the stoichiometry of the reaction and is crucial in identifying the endpoint. It is critical to understand the importance of the equivalence point in titrations to ensure accurate analysis and interpretation of results.

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